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논문 기본 정보

자료유형
학술저널
저자정보
Bo Ra Myoung (Kookmin University) Sam Jin Kim (Kookmin University) Chul Sung Kim (Kookmin University)
저널정보
한국자기학회 Journal of Magnetics Journal of Magnetics Vol.19 No.2
발행연도
2014.6
수록면
126 - 129 (4page)

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초록· 키워드

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We report the crystallographic and magnetic properties of Ni<SUB>0.3</SUB>Fe<SUB>0.7</SUB>Ga₂S₄ by means of X-ray diffractometer (XRD), a superconducting quantum interference device (SQUID) magnetometer, and a Mossbauer spectroscopy. In particular, Ni<SUB>0.3</SUB>Fe<SUB>0.7</SUB>Ga₂S₄ was studied by Mossbauer analysis for evidence of spin reorientation. The chalcogenide material Ni<SUB>0.3</SUB>Fe<SUB>0.7</SUB>Ga₂S₄ was fabricated by a direct reaction method. XRD analysis confirmed that Ni<SUB>0.3</SUB>Fe<SUB>0.7</SUB>Ga₂S₄ has a 2-dimension (2-D) triangular lattice structure, with space group P-3m1. The Mossbauer spectra of Ni<SUB>0.3</SUB>Fe<SUB>0.7</SUB>Ga₂S₄ at spectra at various temperatures from 4.2 to 300 K showed that the spectrum at 4.2 K has a severely distorted 8-line shape, as spin liquid. Electric quadrupole splitting, EQ has anomalous twopoints of temperature dependence of EQ curve as freezing temperature, T<SUB>f</SUB> = 11 K, and Neel temperature, T<SUB>N</SUB> = 26 K. This suggests that there appears to be a slowly-fluctuating “spin gel” state between T<SUB>f</SUB> and T<SUB>N</SUB>, caused by non-paramagnetic spin state below T<SUB>N</SUB>. This comes from charge re-distribution due to spin-orientation above T<SUB>f</SUB>, and T<SUB>N</SUB>, due to the changing EQ at various temperatures. Isomer shift value (0.7 mm/s ≤ δ ≤ 0.9 mm/s) shows that the charge states are ferrous (Fe<SUP>2+</SUP>), for all temperature range. The Debye temperature for the octahedral site was found to be Θ<SUB>D</SUB> = 260 K.

목차

1. Introduction
2. Experimental Details
3. Results and Discussion
4. Conclusions
References

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