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논문 기본 정보
- 자료유형
- 학술저널
- 저자정보
- 저널정보
- 한국미생물생명공학회 Journal of Microbiology and Biotechnology Journal of Microbiology and Biotechnology 제28권 제5호
- 발행연도
- 2018.1
- 수록면
- 732 - 738 (7page)
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초록· 키워드
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Novel carbon-based solid acid catalysts were synthesized through a sustainable route from lipid-extracted microalgal residue of Dunaliella tertiolecta, for biodiesel production. Two carbon-based solid acid catalysts were prepared by surface modification of bio-char with sulfuric acid (H2SO4) and sulfuryl chloride (SO2Cl2), respectively. The treated catalysts were characterized and their catalytic activities were evaluated by esterification of oleic acid. The esterification catalytic activity of the SO2Cl2-treated bio-char was higher (11.5 mmol Prod.∙h-1∙g Cat. -1) than that of commercial catalyst silica-supported Nafion SAC-13 (2.3 mmol Prod.∙h-1∙g Cat. -1) and H2SO4-treated bio-char (5.7 mmol Prod.∙h-1∙g Cat. -1). Reusability of the catalysts was examined. The catalytic activity of the SO2Cl2-modified catalyst was sustained from the second run after the initial activity dropped after the first run and kept the same activity until the fifth run. It was higher than that of first-used Nafion. These experimental results demonstrate that catalysts from lipid-extracted algae have great potential for the economic and environmentfriendly production of biodiesel.
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참고문헌 (34)
참고문헌 신청
Chisti Y / 2007 / Biodiesel from microalgae / Biotechnol. Adv. 25:294~306
Jonker J / 2013 / Techno-economic assessment of micro-algae as feedstock for renewable bio-energy production / Appl. Energy 102:461~475
Mata TM / 2010 / Microalgae for biodiesel production and other applications: a review / Renew. Sustain. Energy Rev. 14:217~232
Pinzi S / 2009 / The ideal vegetable oil-based biodiesel composition: a review of social, economical and technical implications / Energy Fuels 23:2325~2341
Park H / 2016 / Theoretical calculations on the feasibility of microalgal biofuels: utilization of marine resources could help realizing the potential of microalgae / Biotechnol. J. 11:1461~1470
Jonker J / 2013 / Techno-economic assessment of micro-algae as feedstock for renewable bio-energy production / Appl. Energy 102:461~475
Mata TM / 2010 / Microalgae for biodiesel production and other applications: a review / Renew. Sustain. Energy Rev. 14:217~232
Pinzi S / 2009 / The ideal vegetable oil-based biodiesel composition: a review of social, economical and technical implications / Energy Fuels 23:2325~2341
Park H / 2016 / Theoretical calculations on the feasibility of microalgal biofuels: utilization of marine resources could help realizing the potential of microalgae / Biotechnol. J. 11:1461~1470
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