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논문 기본 정보

자료유형
학술저널
저자정보
Rahmini (Chungbuk National University) Soyoung Juhn (Nature Costech) Hyun-A Seong (Chungbuk National University) Soo-Jeong Shin (Chungbuk National University)
저널정보
한국펄프·종이공학회 펄프·종이기술 펄프·종이기술 제52권 제2호(통권 제193호)
발행연도
2020.4
수록면
78 - 86 (9page)
DOI
10.7584/JKTAPPI.2020.04.52.2.78

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초록· 키워드

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Cellulose nanofibrils (CNFs) hydrogels have been used in various applications due to their ability to form gels via entanglement networks in water. In this study, the rheological properties of CNF gel with various concentrations of divalent cations (Mg<SUP>2+</SUP>, Ca<SUP>2+</SUP>, and Ba<SUP>2+</SUP>) are investigated using a rheometer (MCR 102, Anton Paar, Austria). The addition of divalent cations significantly increased the viscosity, storage modulus, and loss modulus as the concentration of cation increased from 100 to 8,000 ppm that contributed to the formation of stronger gels. This phenomenon indicates that higher cation concentration leads to fibril aggregation and a stiffened network. However, when an excessive amount of cations (10,000 ppm) is added, the CNF starts to coagulate and lose strength. Compared to Ca<SUP>2+</SUP> and Ba<SUP>2+</SUP>, Mg<SUP>2+</SUP> has a greater effect on hydrogel strength at 100 ppm, and thus exhibited maximum strength at 5,000 ppm. The maximum strength of Ca<SUP>2+</SUP> occurred at 8,000 ppm, and Ca<SUP>2+</SUP> produced the strongest gel (Mg<SUP>2+</SUP> and Ba<SUP>2+</SUP> were second and third, respectively) between 500 and 1,000 ppm. Ba<SUP>2+</SUP> produced the highest-strength gel with the maximum strength achieved at 8,000 ppm. The impact of divalent ions on the rheological properties of CNF strongly correlated with the kind of cation used and the cation concentration.

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ABSTRACT
1. Introduction
2. Materials and Methods
3. Results and Discussion
4. Conclusions
Literature Cited

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UCI(KEPA) : I410-ECN-0101-2020-586-000604701