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논문 기본 정보
- 자료유형
- 학술저널
- 저자정보
- 저널정보
- 한양대학교 세라믹공정연구센터 Journal of Ceramic Processing Research Journal of Ceramic Processing Research 제20권 제6호
- 발행연도
- 2019.1
- 수록면
- 609 - 616 (8page)
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The optimum powder to ball ratio was examined, which is one of the important conditions in reactive mechanical grinding processing. Yttria (Y2O3)-stabilized zirconia (ZrO2) (YSZ), Ni, and graphene were chosen as additives to enhance the hydriding and dehydriding rates of Mg. Samples with a composition of 92.5 wt% Mg + 2.5 wt% YSZ + 2.5 wt% Ni + 2.5 wt% graphene (designated as Mg-2.5YSZ-2.5Ni-2.5graphene) were prepared by grinding in hydrogen atmosphere. Mg-2.5YSZ-2.5Ni2.5graphene had a high effective hydrogen-storage capacity of almost 7 wt% (6.85 wt%) at 623 K in 12 bar H2 at the second cycle (n = 2). Mg-2.5YSZ-2.5Ni-2.5graphene contained Mg2Ni phase after hydriding-dehydriding cycling. Mg-2.5YSZ-2.5Ni2.5graphene had a larger quantity of hydrogen absorbed for 60 min, Ha (60 min), than Mg-2.5Ni-2.5graphene and Mg2.5graphene. The addition of YSZ also increased the initial dehydriding rate and the quantity of hydrogen released for 60 min, Hd (60 min), compared with those of Mg-2.5Ni-2.5graphene. Y2O3-stabilized ZrO2, Ni, and graphene-added Mg had a higher initial hydriding rate and a larger Ha (60 min) than Fe2O3, MnO, or Ni and Fe2O3-added Mg at n = 1.
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참고문헌 (43)
참고문헌 신청
송명엽 / 2013 / Formation of a High Pressure Form of Magnesium Hydride γ-MgH2 by Mechanical Grinding under Low Hydrogen Pressure / 대한금속·재료학회지 51(2):119~123
Y. Wang / 2019 / Int. J. Hydrogen Energy 44(29):15239~15245
S. Niyomsoan / 2019 / Int. J. Hydrogen Energy 44(29):23257~23266
M. Y. Song / 2019 / Int. J. Hydrogen Energy 44(29):3779~3789
Y. J. Kwak / 2018 / J. Nanosci. Nanotech 18(9):6040~6046
Y. Wang / 2019 / Int. J. Hydrogen Energy 44(29):15239~15245
S. Niyomsoan / 2019 / Int. J. Hydrogen Energy 44(29):23257~23266
M. Y. Song / 2019 / Int. J. Hydrogen Energy 44(29):3779~3789
Y. J. Kwak / 2018 / J. Nanosci. Nanotech 18(9):6040~6046
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