Preparation of Regenerated Cellulose Fiber via Carbonation. I. Carbonation and Dissolution in an Aqueous NaOH Solution

Oh, Sang Youn; Yoo, Dong Il; Shin, Younsook; Lee, Wha Seop; Jo, Seong Mu

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자료유형: 학술저널

저자정보: Oh, Sang Youn (Department of Textile Enginnering, Chonnam National University) Yoo, Dong Il (Department of Textile Enginnering, Chonnam National University) Shin, Younsook (Department of Colthing and Textilies, Chonnam National University) Lee, Wha Seop (Ploymer Hybrid Research Center, Korea Institute of Science and Technology) Jo, Seong Mu (Ploymer Hybrid Research Center, Korea Institute of Science and Technology)

저널정보: 한국섬유공학회 Fibers and Polymers Fibers and polymers 제3권 제1호

발행연도: 2002.1

수록면: 1 - 7 (7page)

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Cellulose carbonate was prepared by the reaction of cellulose pulp and $CO_2$ with treatment reagents, such as aqueous $Zncl_2$ (20-40 wt%) solution, acetone or ethyl acetate, at -5-$0^{\circ}C$ and 30-40 bar ($CO_2$) for 2 hr. Among the treatment reagents, ethyl acetate was the most effective. Cellulose carbonate was dissolved in 10% sodium hydroxide solution containing zinc oxide up to 3 wt% at -5-$0^{\circ}C$. Intrinsic viscosities of raw cellulose and cellulose carbonate were measured with an Ubbelohde viscometer using 0.5 M cupriethylenediamine hydroxide (cuen) as a solvent at $20^{\circ}C$ according to ASTM D1795 method. The molecular weight of cellulose was rarely changed by carbonation. Solubility of cellulose carbonate was tested by optical microscopic observation, UV absorbance and viscosity measurement. Phase diagram of cellulose carbonate was obtained by combining the results of solubility evaluation. Maximum concentration of cellulose carbonate for soluble zone was increased with increasing zinc oxide content. Cellulose carbonate solution in good soluble zone was transparent and showed the lowest absorbance and the highest viscosity. The cellulose carbonate and its solution were stable in refrigerator (-$5^{\circ}C$ and atmospheric pressure).

#Cellulose carbonate #$CO_2$ #Sodium hydroxide solution #Solubility #Phase diagram

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