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The degradation characteristics of 2-chlorophenol(2-CP) by Ferrate(VI) were studied. The degradation efficiency of 2-CP in aqueous solution was investigated at various values of pH, Fe(VI) dosage, initial concentration and aqueous solution temperature. The maximum degradation efficiencies of 2-CP were obtained at pH 7.0 and aqueous solution temperature of 25$^{\circ}C$. The degradation efficiency was proportional to dosage of Fe(VI). Also, the initial rate constant of 2-CP degradation increased with decreasing of the 2-CP initial concentration. In addition, the degradation pathway study for 2-CP was conducted with GC-MS analysis. Acetic acid, formic acid, benzaldehyde and benzoic acid were identified as reaction intermediates of the 2-CP degradation by Ferrate(VI).
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참고문헌 (31)
참고문헌 신청
Carr, J. D / 1985 / Properties of ferrate(VI) in aqueous solution : an alternative oxidant in wastewater treatmen / Proc. Conf. Water Chlorin. Chem. Environ. Impact Health Effects :1285~1298
Christelle Briois / 2006 / Experimental study on the thermal oxidation of 2-chlorophenol in air over the temperaturerange 450∼900℃ / Chemosphere 62:1806~1816
C. Kim / 2004 / kinetics of Bisphenol A Removal by Ferrate (Fe(VI)) Oxidation / Journal of Korean Society on Water Quality
EPA homepage
Galina Matafonova / 2008 / Degradation of chlorophenols in aqueous media using UV XeBr excilamp in a flow-through reactor / Chemosphere 70:1124~1127
Christelle Briois / 2006 / Experimental study on the thermal oxidation of 2-chlorophenol in air over the temperaturerange 450∼900℃ / Chemosphere 62:1806~1816
C. Kim / 2004 / kinetics of Bisphenol A Removal by Ferrate (Fe(VI)) Oxidation / Journal of Korean Society on Water Quality
EPA homepage
Galina Matafonova / 2008 / Degradation of chlorophenols in aqueous media using UV XeBr excilamp in a flow-through reactor / Chemosphere 70:1124~1127
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