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The concern over the risk of environmental exposure to brominated phenols has been increased and has led the researchers to focus their attention on the study of bromophenol treatment. In this study, the effects of pH and ferrate(VI) dose on the degradation of 2-bromophenol were investigated. The results indicated that the oxidation of 2-bromophenol by liquid ferrate(VI) was found to be highly sensitive to the pH condition. Furthermore, the highest removal efficiency was observed at the neutral condition with the removal efficiency of 94.2%. In addition, experimental results showed that 2-bromophenol removal efficiency increased with increasing of ferrate dosage. Ferrate(VI) dose of 0.23 mM was sufficient to remove most of the 2-bromophenol with the efficiency of 99.73% and kapp value of $2982M^{-1}s^{-1}$. Seven compounds were identified as the intermediate products by the GC/MS analysis.
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참고문헌 (31)
참고문헌 신청
Abdullah Al-Abduly / 2014 / Oxidation of benzothiophene, dibenzothiophene, and methyl-dibenzothiophene by ferrate(VI) / Journal of Hazardous Materials 279:296~301
Chengchun, J. / 2008 / Preparation of Potassium Ferrate by Wet Oxidation Method Using Waste Alkali: Purification and Reuse of Waste Alkali / Ferrates 985:5~94
Adele Dell'Erba / 2007 / Disinfection by-products formation during wastewater disinfection with peracetic acid / Desalination 215(1-3):177~186
Catherine S. Evans / 2005 / Mechanisms of Dioxin Formation from the High-Temperature Oxidation of 2-Bromophenol / Environmental Science & Technology 39(7):2128~2134
Graham, N. / 2004 / The influence of pH on the degradation of phenol and chlorophenols by potassium ferrate / Chemosphere 56(10):949~956
Chengchun, J. / 2008 / Preparation of Potassium Ferrate by Wet Oxidation Method Using Waste Alkali: Purification and Reuse of Waste Alkali / Ferrates 985:5~94
Adele Dell'Erba / 2007 / Disinfection by-products formation during wastewater disinfection with peracetic acid / Desalination 215(1-3):177~186
Catherine S. Evans / 2005 / Mechanisms of Dioxin Formation from the High-Temperature Oxidation of 2-Bromophenol / Environmental Science & Technology 39(7):2128~2134
Graham, N. / 2004 / The influence of pH on the degradation of phenol and chlorophenols by potassium ferrate / Chemosphere 56(10):949~956
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