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논문 기본 정보

자료유형
학술저널
저자정보
Daekun Kim (University of Tennessee) Jeong-Gil Nam (Mokpo Maritime University)
저널정보
한국마린엔지니어링학회 Journal of Advanced Marine Engineering and Technology (JAMET) 한국마린엔지니어링학회지 제45권 제1호
발행연도
2021.2
수록면
10 - 16 (7page)
DOI
10.5916/jamet.2021.45.1.10

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초록· 키워드

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Regulations on environmental pollution caused by automobile exhaust gases are becoming increasingly stringent worldwide. Additionally, according to the most recent United States Environmental Protection Agency standard, Tier 3 regulations, the durability requirements for after-treatment have increased from 120,000 to 150,000 miles. The main causes of shortening the life of the catalyst are the sintering of precious metals by high temperature and poisoning by the strong adsorption of impurities. In particular, sulfur, phosphorus, and zinc contained in lubricant additives are the main causes of catalyst life reduction. It is known that the degradation of catalyst performance due to sulfur poisoning is reversible through a high-temperature desulfation process. However, the catalysts exposed to a high temperature in this process, especially three-way catalysts (TWCs) containing oxygen storage capacity (OSC) materials, adversely affect the catalyst performance due to CeO₂ agglomeration and sintering of precious metal particles. Therefore, the purpose of this study was to investigate the effect of the high-temperature desulfation process on the performance of Pd-based TWCs. A gasoline engine bench called Genset was used to perform accelerated thermal aging and lubricant additive poisoning of the TWCs for 24 h at a catalyst temperature of 700°C. Once the accelerated thermal aging and poisoning TWC samples were obtained, the desulfation process at high temperature and evaluations of TWC performance (temperature sweep and OSC) were carried out in a bench flow reactor using simulated engine exhaust gases. For the accelerated thermal aging TWC sample, the conversion of NO, CO, C3H6, and C3H8 after desulfation was similar to that before desulfation, but the OSC decreased by up to 22%. However, the accelerated poisoning TWC sample was found to have improved the conversion of NO, CO, C₃H<SUB>6</SUB>, and C₃H<SUB>8</SUB> and the performance of OSC after desulfation.

목차

Abstract
1. Introduction
2. Experimental Apparatus and Procedure
3. Results and Discussion
4. Conclusions and Recommendation
References

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