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논문 기본 정보
- 자료유형
- 학술저널
- 저자정보
- 저널정보
- 한국고분자학회 폴리머 폴리머 제45권 제2호
- 발행연도
- 2021.3
- 수록면
- 294 - 302 (9page)
- DOI
- 10.7317/pk.2021.45.2.294
이용수
초록· 키워드
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In this work, poly(ethylene succinate-co-0.3 m% ethylene oxalate-co-0.6 m% diethylene glycol succinate) (PEED) and poly(ethylene succinate-co-0.6 m% diethylene glycol succinate) (PED) with a similar weight-average molar mass (M<SUB>w</SUB>) of about 6×104 g/mol were synthesized by a two-step melt polycondensation method to investigate whether the strong-acting ethylene oxalate groups in the molecular chain of poly(ethylene succinate) (PES) could improve the crystallization rate and physical properties of PES. As a result, PEED crystallized faster under isothermal melt crystallization condition and the density of PEED spherulites also increased, indicating ethylene oxalate significantly acted as a nucleating agent. Relative to PED, PEED presented a similar tensile strength, yet it"s Young’s modulus increased by 13%, and elongation at break increased by 72%, indicating that 0.3 m% of ethylene oxalate could improve the physical properties of PES. This study provides a new strategy for improving the crystallization rate of PES.
목차
Abstract
Introduction
Experimental
Results and Discussion
Conclusions
References
참고문헌 (24)
참고문헌 신청
Abdali, Z.; Logsetty, S.; Liu, S. Bacteria-Responsive Single and Core-Shell Nanofibrous Membranes Based on Polycaprolactone/Poly(ethylene succinate) for On-Demand Release of Biocides. ACS Omega 2019, 4, 4063-4070.
Okur, N. U.; Filippousi, M.; Okur, M. E.; Ayla, S.; Caglar, E. S.; Yoltas, A.; Siafaka, P. I. A Novel Approach for Skin Infections: Controlled Release Topical Mats of Poly(Latic Acid)/Poly (Ethylene Succinate) Blends Containing Voriconazole. J. Drug. Deliv. Sci. Tec. 2018, 46, 74-86.
Teng, S.; Qiu, Z. Enhanced Crystallization and Mechanical Properties of Biodegradable Poly(ethylene succinate) by Octaisobutyl-Polyhedral oligomericsilsesquioxanes in their nanocomposites. Thermochim. Acta 2017, 649, 22-30.
Teng, S. Q.; Jiang, Z. G.; Qiu, Z. B. Effect of Different POSS Structures on the Crystallization Behavior and Dynamic Mechanical Properties of Biodegrable Poly(Ethylene Succinate). Polymer 2018, 163, 68-73.
Vasileiou, A. A.; Papageorgiou, G. Z.; Kontopoulou, M.; Docoslis, A.; Bikiaris, D. Covalently Bonded Poly(Ethylene Succinate)/SiO2 Nanocomposites Prepared by In Situ Polymerization, Polymer 2013, 54, 1018-1032.
Okur, N. U.; Filippousi, M.; Okur, M. E.; Ayla, S.; Caglar, E. S.; Yoltas, A.; Siafaka, P. I. A Novel Approach for Skin Infections: Controlled Release Topical Mats of Poly(Latic Acid)/Poly (Ethylene Succinate) Blends Containing Voriconazole. J. Drug. Deliv. Sci. Tec. 2018, 46, 74-86.
Teng, S.; Qiu, Z. Enhanced Crystallization and Mechanical Properties of Biodegradable Poly(ethylene succinate) by Octaisobutyl-Polyhedral oligomericsilsesquioxanes in their nanocomposites. Thermochim. Acta 2017, 649, 22-30.
Teng, S. Q.; Jiang, Z. G.; Qiu, Z. B. Effect of Different POSS Structures on the Crystallization Behavior and Dynamic Mechanical Properties of Biodegrable Poly(Ethylene Succinate). Polymer 2018, 163, 68-73.
Vasileiou, A. A.; Papageorgiou, G. Z.; Kontopoulou, M.; Docoslis, A.; Bikiaris, D. Covalently Bonded Poly(Ethylene Succinate)/SiO2 Nanocomposites Prepared by In Situ Polymerization, Polymer 2013, 54, 1018-1032.
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