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논문 기본 정보

자료유형
학술저널
저자정보
Kwanruthai Wongsaprom (Mahasarakham University) Akekapol Winyayong (Mahasarakham University) Supree Pinitsoontorn (Khon Kaen University) Pinit Kidkhunthod (Synchrotron Light Research Institute (Public Organization)) Somchai Sonsupap (Suranaree University of Technology Nakhon Ratchasima) Santi Maensiri (Suranaree University of Technology Nakhon Ratchasima)
저널정보
한국자기학회 Journal of Magnetics Journal of Magnetics Vol.26 No.3
발행연도
2021.9
수록면
256 - 264 (9page)
DOI
10.4283/JMAG.2021.26.3.256

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초록· 키워드

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The nanocrystalline powders of Cr-doped SnO₂ with Cr-dopant concentrations of 2, 4 and 6 wt%, were synthesized by a simple hydrothermal method. XRD results, along with the FT-IR and SAED patterns, confirmed the formation of the SnO₂’s tetragonal phase without other impurity phases. Optical analysis revealed a significant decrease in the energy gap of the doped samples from 3.69 to 3.40 eV. X-ray absorption spectroscopy, including x-ray absorption near-edge spectroscopy, was used to qualitatively investigate the valence states of doped Cr. Room temperature ferromagnetism was observed in Cr-doped SnO₂ samples. The highest value of magnetization was found in SnO₂ doped with 4 wt% of Cr (about 4.88 memu/g) and decreased slightly as the Cr concentration increased. The reduction of magnetization with the increase of Cr content happened because antiferromagnetic Cr-O-Cr super-exchange interaction took place within the nearest Cr<SUP>3+</SUP> ions through O<SUP>2-</SUP> ions. The oxygen vacancies were induced by the ferromagnetism in the Cr-doped SnO₂ nanocrystalline powders.

목차

1. Introduction
2. Experimental Procedure
3. Results and Discussion
4. Conclusion
References

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