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논문 기본 정보
- 자료유형
- 학술저널
- 저자정보
- 저널정보
- 한국고분자학회 폴리머 폴리머 제46권 제1호
- 발행연도
- 2022.1
- 수록면
- 6 - 12 (7page)
- DOI
- 10.7317/pk.2022.46.1.6
이용수
초록· 키워드
오류제보하기
Reducing Payne effect of natural rubber (NR) composite has been a major challenge in composite’s preparation. In this work, the composite based on NR and sepiolite was focused. Reduction of Payne effect was successfully performed by introducing modified palm stearin (mo-PS) as compatibilizer. Sepiolite was fixed at 20 phr whereby the mo-PS was ranged from 0-3 phr. The properties were studied through curing characteristics, tensile properties and dynamic properties. The presence of certain functionalities of mo-PS was corroborated by Fourier transform infrared (FTIR) analysis. From cure properties, scorch and curing times decreased as a function of mo-PS due to the role of mo-PS as a secondary curing additive in vulcanization process. It was also found that mo-PS improved modulus and tensile strength of composites. The improvement was due to improved NR-sepiolite interactions arising from hydrogen bonds formed in presence of mo-PS. This was clearly verified by observing the Payne effect.
목차
Abstract
Introduction
Experimental
Results and Discussion
Conclusions
References
참고문헌 (27)
참고문헌 신청
Arrighi, V.; McEwen, I. J.; Qian, H.; Serrano Prieto, M. B. The Glass Transition and Interfacial Layer in Styrene-butadiene Rubber Containing Silica Nanofiller. Polymer 2003, 44, 6259-6266.
Hayeemasae, N.; Ismail, H.; Azura, A. R. Recycled Polyethylene Terephthalate Filled Natural Rubber Compounds: Effects of Filler Loading and Types of Matrix. J. Elastomers Plast. 2011, 43, 429-449.
Zhong, B.; Jia, Z.; Luo, Y.; Jia, D.; Liu, F. Understanding the Effect of Filler Shape Induced Immobilized Rubber on the Interfacial and Mechanical Strength of Rubber Composites. Polym. Test. 2017, 58, 31-39.
Velez, J. S.; Velasquez, S.; Giraldo, D. Mechanical and Rheometric Properties of Gilsonite/Carbon Black/Natural Rubber Compounds Cured Using Conventional and Efficient Vulcanization Systems. Polym. Test. 2016, 56, 1-9.
Poh, B. T.; Suid, N. H. Effect of Zinc Oxide on the Viscosity and Adhesion Property of Epoxidized Natural Rubber/Acrylonitrile-butadiene Rubber-based Pressure-sensitive Adhesives. J. Vinyl Addit. Technol. 2016, 22, 410-414.
Hayeemasae, N.; Ismail, H.; Azura, A. R. Recycled Polyethylene Terephthalate Filled Natural Rubber Compounds: Effects of Filler Loading and Types of Matrix. J. Elastomers Plast. 2011, 43, 429-449.
Zhong, B.; Jia, Z.; Luo, Y.; Jia, D.; Liu, F. Understanding the Effect of Filler Shape Induced Immobilized Rubber on the Interfacial and Mechanical Strength of Rubber Composites. Polym. Test. 2017, 58, 31-39.
Velez, J. S.; Velasquez, S.; Giraldo, D. Mechanical and Rheometric Properties of Gilsonite/Carbon Black/Natural Rubber Compounds Cured Using Conventional and Efficient Vulcanization Systems. Polym. Test. 2016, 56, 1-9.
Poh, B. T.; Suid, N. H. Effect of Zinc Oxide on the Viscosity and Adhesion Property of Epoxidized Natural Rubber/Acrylonitrile-butadiene Rubber-based Pressure-sensitive Adhesives. J. Vinyl Addit. Technol. 2016, 22, 410-414.
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UCI(KEPA) : I410-ECN-0101-2022-578-000124924