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논문 기본 정보
- 자료유형
- 학술저널
- 저자정보
- 저널정보
- 한국고분자학회 폴리머 폴리머 제47권 제5호
- 발행연도
- 2023.9
- 수록면
- 606 - 612 (7page)
- DOI
- 10.7317/pk.2023.47.5.606
이용수
초록· 키워드
오류제보하기
In this study, polymerization and characterization of trisalicyl borate (TSB) with epoxidized soybean oil (ESO) was evaluated. Synthesis of TSB is involved by the reaction between boric acid and salicylic acid at the first step of the reaction. Then TSB was polymerized with ESO at 95 ℃ for 6 hours. All the compounds synthesized were characterized by FTIR and 1H NMR techniques. Characteristic bands of the boron esters appeared at 1644, 1610, 1578, 1472, 1276, 784, 757, 656, and 530 cm-1. 1H NMR technique indicated that hydrogens of the free carboxyl groups revealed at 10.8 ppm. The resultant polymers of TSB and ESO were rubbery materials. Mechanical, thermal and electrical properties of the TSB-ESO polymer was determined. They exhibit small stress at break values with high strain percentages. Thermal and mechanical characterization of the polymers were performed by differential scanning calorimetry (DSC), thermogravimetric analysis (TGA) and Stress-Strain tests. It was found that TSB-ESO polymer exhibited highest swelling ratio in toluene. The TSB-ESO polymer was a rubbery material that showed 0.1 MPa stress at break value with 240% elongation. Thermal properties of the synthesized polymer were evaluated with DSC and TGA methods. TSB-ESA showed one Tg at -2 ℃ and a melting peak at 92 ℃. TGA plot showed 2 segmental weight loss. As an indicator for thermal stability, 5% weight loss temperature was measured as 112 ℃. Additionally, DC analysis reveals that the resistivity and conductivity of the polymeric sample is measured as 2.375 MΩm and 0.401 μS/m respectively.
목차
Abstract
Introduction
Experimental
Results and Discussion
Conclusions
References
참고문헌 (22)
참고문헌 신청
Kahraman, C.; Orobello, C.; Cirella, G. T. Changing Dynamics with COVID-19: Future Outlook. In Human Settlements. Advances in 21st Century Human Settlements, Cirella, G.T., Ed.; Springer: Singapore, 2021; pp 235-252.
Lam, D. How the World Survived the Population Bomb: Lessons From 50 Years of Extraordinary Demographic History. Demography 2011, 48, 1231-1262.
Cayli, G.; Kusefoglu, S. Isothiocyanates of Plant Oil Triglycerides: Synthesis, Characterization and Polymerization with Polyols and Polyamines. J. Appl. Polym. Sci. 2010, 116, 125-131.
Park, S. J.; Jin, F. L.; Lee, J. R. Thermal and Mechanical Properties of Tetrafunctinal Epoxy Resin Toughened with Epoxidized Soybean Oil. Mater. Sci. Eng. A 2004, 374, 109-114.
Meier, M. A. R. Merhathesis with Oleochemicals: New Approaches for the Utilization of Plant Oils as Renewable Resources in Polymer Science. Macromol. Chem. Physic. 2019, 210, 1073-1079.
Lam, D. How the World Survived the Population Bomb: Lessons From 50 Years of Extraordinary Demographic History. Demography 2011, 48, 1231-1262.
Cayli, G.; Kusefoglu, S. Isothiocyanates of Plant Oil Triglycerides: Synthesis, Characterization and Polymerization with Polyols and Polyamines. J. Appl. Polym. Sci. 2010, 116, 125-131.
Park, S. J.; Jin, F. L.; Lee, J. R. Thermal and Mechanical Properties of Tetrafunctinal Epoxy Resin Toughened with Epoxidized Soybean Oil. Mater. Sci. Eng. A 2004, 374, 109-114.
Meier, M. A. R. Merhathesis with Oleochemicals: New Approaches for the Utilization of Plant Oils as Renewable Resources in Polymer Science. Macromol. Chem. Physic. 2019, 210, 1073-1079.
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