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논문 기본 정보

자료유형
학위논문
저자정보

이선용 (충남대학교, 忠南大學校 大學院)

지도교수
元鍾虎
발행연도
2013
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충남대학교 논문은 저작권에 의해 보호받습니다.

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이 논문의 연구 히스토리 (2)

초록· 키워드

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The purpose of this study is to get a optimal design of a nitrogen coating device of U-Mo particles surface.

* To the development of nuclear-reactor''s nuclear fuel, nuclear fuel of research nuclear-reactor for the multipurpose should be available such as irradiation safety, reprocessing, and mass production. As an alternative for achieve these conditions, the nitrogen coation method was adopted to inhibit the formation of the reaction layer between U-Mo particles and Al matrix in U-Mo/Al dispersion fuel. Also, the nitrogen coation equipment was designed consider of the effective formation of the nitrogen coating layer. The initial design of the device, it was composed of a cylindrical metal chamber, rotation motor, cooling jacket, electric furnace of tube type, vacuum pump, and gas injection control device. The core of this device is cylindrical metal chamber. The cylindrical metal chamber is made of ZrO2 with thickness of about 5 mm. And, the inside diameter of the chamber is about 55 mm and length is 195 mm. As the experimental results, the thickness of nitrogen coating was about 250 ㎚ (set temp. of 900 ℃) and 500 ㎚ (set temp. of 1000 ℃) with an increase of temperature. Therefore, the thickness of nitrogen coating was increased with an increase of temperature. Also, crystal structure was similar to the U-Mo when increases the temperature and reaction time. The second design of the device, cylindrical metal chamber was modified. Modification has installed four rods inside the chamber. The purpose of rod installation is to increase the contact of the nitrogen and U-Mo, and increase the mixing ratio of U-Mo. As a result, the reaction time was reduced when made the same thickness of the coating layer at the U-Mo particles surface. In order to improve these functions, equipment is designed such as fluidized bed reactor and impeller type reactor. But, the fluidized bed reactor and impeller type reactor was did not enhance because their function is limited by various factors such as the material or structure of the equipment.

목차

1. 서 론 1
1.1 연구배경 1
1.2 연구동향 5
1.2.1 연구용 원자로의 핵연료 제조 현황 5
1.2.2 핵연료 기술의 국내외 개발현황 및 기술수준 6
1.2.3 질화물 처리된 U-Mo 핵연료 8
1.3 연구의 목적 10
2. 이론 12
2.1 질소 원자의 성질 12
2.2 질소 고용도 13
2.3 금속 우라늄 특성 15
2.4 질화법의 종류 16
3. 실험장치 및 실험방법 18
3.1 실험 재료 18
3.2 실험 장치 18
3.3 실험 방법 24
4. 실험결과 27
4.1 우라늄 분말 제조 27
4.2 1차 설계에 의한 우라늄 질화코팅장치 성능 평가 31
4.3 2차 설계에 의한 우라늄 질화코팅장치 성능 평가 36
4.4 12차 설계 문제점 향상에 대한 제언 43
5. 결론 49
References 51
ABSTRACT 54

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