목차

Contents
List of Table titles
List of Figure captions
Abstract
Chapter 1. Introduction
1.1. Ionomers 2
1.1.1. Definitions 2
1.1.2. General background 2
1.1.3. Main techniques used in this work 3
1.1.4. Synthesis 7
1.1.5. Morphological models 8
1.2. Structure of This Thesis and Brief Experination of Each Chapter 10
1.3. References 13
Chapter 2. Ionomers
2.1. Introduction 18
2.2. Multiplets and Clusters 24
2.3. Glass Transition Tempseratures 29
2.3.1. Glass transition of matrix region 29
2.3.2. Glass transition of cluster regions 31
2.4. Physical Properties of Various Ionomers 32
2.4.1. Polyethylene-based ionomer 32
2.4.2. Polytetrafluoroethylene-based ionomers 36
2.4.3. Polystyrene ionomer 39
2.5. Plasticization 44
2.6. Ionomer Blend 47
2.7. Applications of Ionomers 54
2.7.1. Superpermeselective membrans 54
2.7.2. Ionomer plastics 55
2.7.3. Ionomeric elastomers 55
2.7.4. Compatibilizer 57
2.7.5. Ionomeric nanocomposites 59
2.7.6. Drilling fluids 60
2.7.7. Ionomer coatings 61
2.7.8. Ionic polymer-metal composites 61
2.7.9. Biomaterials 62
2.7.10. Self-healing smart materials 64
2.7.11. Shape-memory ionomers 67
2.7.12. Catalysis or catalytic supports 69
2.7.13. Anti-static materials 69
2.8. References 71
Chapter 3. Tangible plasticization/filler effects of sodium salts of dimer acids on the mechanical properties of styrene ionomers
3.1. Introduction 107
3.2. Experimental Section 110
3.3. Results and Discussion 113
3.4. Conclusions 129
3.5. References 124
Chapter 4. Detailed interpretation of the dynamic mechanical and morphological data of poly(styrene-co-sodium sulfopropyl methacrylate) ionomers
4.1. Introduction 134
4.2. Experimental Section 137
4.3. Results 138
4.4. Discussion 150
4.5. Conclusions 150
4.6. References 161
Chapter 5. Effects of low-temperature dehydration on poly(styrene-co-styrenesulfonic acid) membrane
5.1. Introduction 165
5.2. Experimental Section 166
5.3. Results and Discussion 168
5.4. Conclusions 177
5.5. References 179
Appendixes
Acknowledgement