목차

Abstract i
Contents v
List of Tables and Figures viii
1. Introduction 1
2. Experiments 4
2.1. Materials 4
2.2. Synthesis of Monomers with Terephthalamide Structure 5
2.2.1. Ethanolamine-DMT-Ethanolamine (EDE) Trimer 5
2.2.2. Propanolamine-DMT-Propanolamine (PDP) Trimer 5
2.2.3. DMT-Cadaverine-DMT (DCD) X-mer 6
2.2.4. MCCB-Cadaverine-MCCB (MCM) Trimer 7
2.2.5. Tyramine-TCL-Tyramine (TTT) Trimer 9
2.2.6. Ethanol-Tyramine-TCL-Tyramine-Ethanol Pentamer 9
2.3. Synthesis of Aliphatic Diol Monomers Containing Amide Bonds 12
2.3.1. Dimethyl Malonate Based Diol (EME/PMP) 12
2.3.2. Dimethyl Succinate Based Diol (ESE/PSP) 13
2.3.3. Dimethyl Adipate Based Diol (EAE/PAP) 13
2.3.4. Dimethyl Suberate Based Diol (ESuE/PSuP) 14
2.4. Solution Polymerization of Poly(ester-amide)s 17
2.4.1. Polymerization with Terephthalamide Structure Monomers 17
2.4.1.1. EDE Trimer 17
2.4.1.2. MCM Trimer 17
2.4.1.3. TTT Trimer 19
2.4.2. Polymerization with Aliphatic Diol Monomers 19
2.5. Thermal Bulk Polymerization of Poly(ester-amide)s 20
2.5.1. Polymerization with Terephthalamide Structure Monomers 21
2.5.1.1. EDE/PDP Trimer, EG, and DMT Terpolymer 21
2.5.1.2. DCD X-mer Based Poly(ester-amide)s 24
2.5.1.3. Acetylation of TTT Trimer for Polymerization of Poly(ester-amide)s 26
2.5.2. Polymerization with Aliphatic Diol Monomers 26
2.5.2.1. Large Scale Polymerization for Preparation of Tensile Test Specimens 28
2.6. Characterization 29
2.7. Thermal Properties 30
2.8. Mechanical Properties 31
3. Results and Discussion 32
3.1. Synthesis of Monomers and Polymerization with Terephthalamide 32
3.2. Analyses of Causes of Failure in Thermal Bulk Polymerization and
Establishment of New Experimental Direction 36
3.3. Synthesis of Tailor-made Diols Containing Amide Bonds and Thermal
Properties of Diols 40
3.4. Polymerization of Poly(ester-amide)s with Tailor-made Diols 43
3.5. Establishment of Further Research Direction through Representative Compound Selection and Various Analyses Thereof 46
4. Conclusion 57
5. References 59