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Two-dimensional (2D) ultrathin molybdenum dichalcogenides $MoS_2$ has gained a great deal of attention in energy conversion and storage applications because of its unique morphology and property. The 2D $MoS_2$ nanosheets provide a high specific surface area, 2D charge channel, sub-nanometer thickness, and high conductivity, which lead to high electrochemical performances for energy storage devices. In this paper, an overview of properties and synthetic methods of $MoS_2$ nanosheets for applications of supercapacitors and rechargeable batteries is introduced. Different phases triangle prismatic 2H and metallic octahedral 1T structured $MoS_2$ were characterized using various analytical techniques. Preparation methods were focused on top-down and bottom-up approaches, including mechanical exfoliation, chemical intercalation and exfoliation, liquid phase exfoliation by the direct sonication, electrochemical intercalation exfoliation, microwave-assisted exfoliation, mechanical ball-milling, and hydrothermal synthesis. In addition, recent applications of supercapacitors and rechargeable batteries using $MoS_2$ electrode materials are discussed.
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참고문헌 (48)
참고문헌 신청
M. R. Lukatskaya / 2016 / Multidimensional materials and device architectures for future hybrid energy storage / Nat. Commun 7:12647~12659
M. Salanne / 2016 / Efficient storage mechanisms for building better supercapacitors / Nat. Energy 1:16070~16079
P. Simon / 2014 / Where do batteries end and supercapacitors begin? / Science 343:1210~1211
G. Z. Chen / 2017 / Supercapacitor and supercapattery as emerging electrochemical energy stores / Int. Mater. Rev 62:173~202
X. Xiao / 2018 / Topochemical synthesis of 2D materials / Chem. Soc. Rev 47:8744~8765
M. Salanne / 2016 / Efficient storage mechanisms for building better supercapacitors / Nat. Energy 1:16070~16079
P. Simon / 2014 / Where do batteries end and supercapacitors begin? / Science 343:1210~1211
G. Z. Chen / 2017 / Supercapacitor and supercapattery as emerging electrochemical energy stores / Int. Mater. Rev 62:173~202
X. Xiao / 2018 / Topochemical synthesis of 2D materials / Chem. Soc. Rev 47:8744~8765
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